11:48:57 9 substances 4 substances with unknown enthalpies 4 substances with unknown entropies name ion M i DelfH0 HT-H0 s(H) ST s(S) MnO2- T 86.9 1.0000 0.0 69.4 0.0 0.0 5.0 MnO3- T 102.9 1.0000 0.0 97.2 0.0 0.0 5.2 MnO4- T 118.9 1.0000 0.0 121.9 0.0 0.0 6.9 PtO2- T 227.0 0.3380 0.0 70.8 0.0 0.0 4.9 Substances with known enthalpies Substances with known entropies MnO(s) F 0.0 0.0000 -384.8 66.6 0.5 137.5 3.0 Pt(s) F 0.0 0.0000 0.0 37.5 0.0 85.1 0.5 CrO3- T 100.0 0.8376 -669.0 97.5 9.0 391.7 4.0 CrO4- T 116.0 0.8376 -781.0 119.9 11.0 432.2 5.8 Cr2O6- T 200.0 0.7037 -1237.8 0.0 18.0 600.5 12.0 11:48:57 Covariations H and H 57.00 CrO3- 3 CrO4- 4 45.00 CrO3- 3 Cr2O6- 5 153.00 CrO4- 4 Cr2O6- 5 Covariations H and S 21.00 CrO3- 3 CrO3- 8 44.00 CrO4- 4 CrO4- 9 181.00 Cr2O6- 5 Cr2O6- 10 -11.00 CrO3- 3 Cr2O6- 10 66.00 CrO4- 4 Cr2O6- 10 -11.00 Cr2O6- 5 CrO3- 8 66.00 Cr2O6- 5 CrO4- 9 Covariations S and S -8.00 CrO3- 8 Cr2O6- 10 50.00 CrO4- 9 Cr2O6- 10 ( 1) -1. MnO(s) -2. CrO4- +1. MnO3- +1. Cr2O6- Sum is 6. Mass correction will be 0.172 Tavr b a DelH DelS N P Sp Sf2 1344. 0.37 0.00 1 1430. 0.35 0.01 2 1400. 0.45 0.36 -3.7 +/- 0.0 0.3 +/- 0.0 3.0 0.037 0.01 0.00 1344. 0.70 0.07 4 1387. 0.49 0.13 3 1430. 0.31 0.12 2 1473. 0.29 0.13 3 1515. 0.44 0.07 3 1421. 3.79 0.47 -31.5 +/- 15.1 -18.2 +/- 10.6 15.0 0.122 0.10 0.22 1300. 0.67 0.08 4 1344. 0.61 0.09 5 1387. 0.49 0.08 5 1430. 0.74 0.07 2 1356. 0.89 0.61 -7.4 +/- 21.4 -0.4 +/- 15.8 16.0 0.092 0.08 0.24 All experiments 1388. 3.04 0.53 -25.3 +/- 9.5 -13.9 +/- 6.8 34.0 0.184 0.09 0.21 ( 4) -1. MnO(s) -1. MnO3- -2. CrO3- +2. MnO2- +1. Cr2O6- Sum is 10. Mass correction will be 0.121 Tavr b a DelH DelS N P Sp Sf2 1344. -8.69 0.00 1 1430. -8.02 0.04 2 1400. -14.97 -8.24 124.5 +/- 0.0 20.4 +/- 0.0 3.0 0.037 0.04 0.00 1387. -8.12 0.16 3 1430. -8.24 0.06 2 1473. -8.36 0.09 3 1515. -8.16 0.23 3 1451. 1.35 -8.22 -11.2 +/- 22.5 -76.0 +/- 15.5 11.0 0.078 0.16 0.21 1300. -8.25 0.13 4 1344. -8.19 0.13 5 1387. -7.88 0.09 5 1430. -7.77 0.03 2 1356. -7.67 -8.06 63.8 +/- 15.2 -19.9 +/- 11.2 16.0 0.092 0.11 0.17 All experiments 1394. -0.78 -8.13 6.5 +/- 17.8 -63.0 +/- 12.8 30.0 0.177 0.13 0.38 ( 7) -1. MnO(s) -3. MnO2- -15. MnO4- -12. CrO3- +19. MnO3- +10. CrO4- +1. Cr2O6- Sum is 840. Mass correction will be 0.019 Tavr b a DelH DelS N P Sp Sf2 1387. 0.93 0.22 3 1430. 1.00 0.41 2 1473. 0.95 0.10 3 1515. 0.66 0.21 3 1451. 3.97 0.87 -33.0 +/- 23.8 -15.5 +/- 16.4 11.0 0.078 0.23 0.22 1300. 0.79 0.08 4 1344. 0.83 0.04 5 1387. 0.81 0.05 5 1430. 0.90 0.15 2 1356. -1.03 0.82 8.6 +/- 5.8 13.1 +/- 4.3 16.0 0.092 0.07 0.06 All experiments 1393. -0.03 0.84 0.3 +/- 9.4 7.2 +/- 6.8 27.0 0.173 0.15 0.20 ( 9) -56. Pt(s) -15. MnO2- -17. MnO3- -19. MnO4- -4. CrO3- -6. CrO4- +51. MnO(s) +5. Cr2O6- +56. PtO2- Sum is 4088. Mass correction will be 1.682 Tavr b a DelH DelS N P Sp Sf2 1387. -0.54 0.00 1 1430. 0.00 0.11 2 1473. -0.14 0.08 3 1515. -0.49 0.37 2 1461. 2.19 -0.24 -18.2 +/- 62.5 -14.5 +/- 42.8 8.0 0.055 0.20 0.42 All experiments 1461. 2.19 -0.24 -18.2 +/- 62.5 -14.5 +/- 42.8 8.0 0.055 0.20 0.42 Overall there are 9 reactions 11:48:57 Inverting is over 11:48:57 Solution is found 11:48:57 i DelHcor DelHest dif DelScor DelSest dif DelH DelS S1 1 168.1 189.7 -21.6 284.2 285.5 -1.2 -25.3 -13.9 0.27 2 195.9 189.7 6.2 283.5 283.5 0.0 -25.3 -13.9 0.09 3 171.8 189.7 -17.9 290.1 289.9 0.2 -25.3 -13.9 0.23 4 -53.8 64.2-118.0 83.2 84.2 -0.9 6.5 -63.0 0.55 5 81.9 64.2 17.7 81.7 82.6 -0.9 6.5 -63.0 0.39 6 6.9 64.2 -57.3 86.5 85.7 0.8 6.5 -63.0 0.74 7 9.8 -23.5 33.3 -11.6 -11.9 0.2 0.3 7.2 0.33 8 -31.8 -23.5 -8.3 -13.2 -13.0 -0.2 0.3 7.2 0.12 9 -267.5 -267.5 0.0 -214.6 -214.6 0.0 -18.2 -14.5 0.00 Standart error of fitting is 0.36 Degrees of freedom are 10 DelfHT DelfH0 sr sold ssum MnO2- -333.7 -403.1 65.8 15.6 67.6 MnO3- -464.6 -561.8 78.6 14.0 79.9 MnO4- -567.1 -689.0 113.5 18.0 114.9 PtO2- -117.5 -188.3 140.7 14.0 141.4 S sr sold ssum MnO2- 244.4 47.3 10.9 48.6 MnO3- 367.5 56.7 9.4 57.5 MnO4- 408.3 81.7 12.5 82.7 PtO2- 279.6 97.6 8.9 98.0 MnO2- MnO3- MnO4- PtO2- MnO2- MnO3- MnO4- PtO2- MnO2- 4572. 3268. 3159. 3309. 3246. 2310. 2228. 2338. MnO3- 3268. 6380. 7430. 5349. 2310. 4548. 5302. 3806. MnO4- 3159. 7430.13196. 7590. 2228. 5302. 9442. 5414. PtO2- 3309. 5349. 7590.19994. 2338. 3806. 5414.13820. MnO2- 3246. 2310. 2228. 2338. 2358. 1686. 1627. 1696. MnO3- 2310. 4548. 5302. 3806. 1686. 3304. 3849. 2759. MnO4- 2228. 5302. 9442. 5414. 1627. 3849. 6834. 3918. PtO2- 2338. 3806. 5414.13820. 1696. 2759. 3918. 9612. MnO(s) 0. 0. 0. 0. 0. 0. 0. 0. Pt(s) 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 93. 69. 45. 69. 32. 11. -10. 11. CrO4- 25. 89. 153. 89. -22. 22. 66. 22. Cr2O6- -126. -18. 90. -18. -126. -49. 28. -49. MnO(s) 0. 0. 0. 0. 9. 9. 9. 0. Pt(s) 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 32. 11. -10. 11. 24. 8. -8. 8. CrO4- -22. 22. 66. 22. -16. 17. 51. 17. Cr2O6- -126. -49. 28. -49. -102. -44. 14. -44. All done 11:48:57