16:14:52 9 substances 4 substances with unknown enthalpies 0 substances with unknown entropies name ion M i DelfH0 HT-H0 s(H) ST s(S) Substances with known entropies MnO2- T 86.9 1.0000 0.0 69.4 0.0 343.2 5.0 MnO3- T 102.9 1.0000 0.0 97.2 0.0 384.5 5.2 MnO4- T 118.9 1.0000 0.0 121.9 0.0 422.7 6.9 PtO2- T 227.0 0.3380 0.0 70.8 0.0 362.1 4.9 Substances with known enthalpies MnO(s) F 0.0 0.0000 -384.8 66.6 0.5 137.5 3.0 Pt(s) F 0.0 0.0000 0.0 37.5 0.0 85.1 0.5 CrO3- T 100.0 0.8376 -669.0 97.5 9.0 391.7 4.0 CrO4- T 116.0 0.8376 -781.0 119.9 11.0 432.2 5.8 Cr2O6- T 200.0 0.7037 -1237.8 0.0 18.0 600.5 12.0 16:14:54 Covariations H and H 57.00 CrO3- 3 CrO4- 4 45.00 CrO3- 3 Cr2O6- 5 153.00 CrO4- 4 Cr2O6- 5 Covariations H and S 21.00 CrO3- 3 CrO3- 12 44.00 CrO4- 4 CrO4- 13 181.00 Cr2O6- 5 Cr2O6- 14 -11.00 CrO3- 3 Cr2O6- 14 66.00 CrO4- 4 Cr2O6- 14 -11.00 Cr2O6- 5 CrO3- 12 66.00 Cr2O6- 5 CrO4- 13 Covariations S and S -8.00 CrO3- 12 Cr2O6- 14 50.00 CrO4- 13 Cr2O6- 14 ( 1) -1. MnO(s) -2. CrO4- +1. MnO3- +1. Cr2O6- Sum is 6. Mass correction will be 0.172 Tavr b a DelH DelS N P Sp Sf2 1344. 0.37 0.00 1 1430. 0.35 0.01 2 1400. 0.45 0.36 -3.7 +/- 0.0 0.3 +/- 0.0 3.0 0.037 0.01 0.00 1344. 0.70 0.07 4 1387. 0.49 0.13 3 1430. 0.31 0.12 2 1473. 0.29 0.13 3 1515. 0.44 0.07 3 1421. 3.79 0.47 -31.5 +/- 15.1 -18.2 +/- 10.6 15.0 0.122 0.10 0.22 1300. 0.67 0.08 4 1344. 0.61 0.09 5 1387. 0.49 0.08 5 1430. 0.74 0.07 2 1356. 0.89 0.61 -7.4 +/- 21.4 -0.4 +/- 15.8 16.0 0.092 0.08 0.24 All experiments 1388. 3.04 0.53 -25.3 +/- 9.5 -13.9 +/- 6.8 34.0 0.184 0.09 0.21 ( 4) -1. MnO(s) -1. MnO3- -2. CrO3- +2. MnO2- +1. Cr2O6- Sum is 10. Mass correction will be 0.121 Tavr b a DelH DelS N P Sp Sf2 1344. -8.69 0.00 1 1430. -8.02 0.04 2 1400. -14.97 -8.24 124.5 +/- 0.0 20.4 +/- 0.0 3.0 0.037 0.04 0.00 1387. -8.12 0.16 3 1430. -8.24 0.06 2 1473. -8.36 0.09 3 1515. -8.16 0.23 3 1451. 1.35 -8.22 -11.2 +/- 22.5 -76.0 +/- 15.5 11.0 0.078 0.16 0.21 1300. -8.25 0.13 4 1344. -8.19 0.13 5 1387. -7.88 0.09 5 1430. -7.77 0.03 2 1356. -7.67 -8.06 63.8 +/- 15.2 -19.9 +/- 11.2 16.0 0.092 0.11 0.17 All experiments 1394. -0.78 -8.13 6.5 +/- 17.8 -63.0 +/- 12.8 30.0 0.177 0.13 0.38 ( 7) -1. MnO(s) -3. MnO2- -15. MnO4- -12. CrO3- +19. MnO3- +10. CrO4- +1. Cr2O6- Sum is 840. Mass correction will be 0.019 Tavr b a DelH DelS N P Sp Sf2 1387. 0.93 0.22 3 1430. 1.00 0.41 2 1473. 0.95 0.10 3 1515. 0.66 0.21 3 1451. 3.97 0.87 -33.0 +/- 23.8 -15.5 +/- 16.4 11.0 0.078 0.23 0.22 1300. 0.79 0.08 4 1344. 0.83 0.04 5 1387. 0.81 0.05 5 1430. 0.90 0.15 2 1356. -1.03 0.82 8.6 +/- 5.8 13.1 +/- 4.3 16.0 0.092 0.07 0.06 All experiments 1393. -0.03 0.84 0.3 +/- 9.4 7.2 +/- 6.8 27.0 0.173 0.15 0.20 ( 9) -56. Pt(s) -15. MnO2- -17. MnO3- -19. MnO4- -4. CrO3- -6. CrO4- +51. MnO(s) +5. Cr2O6- +56. PtO2- Sum is 4088. Mass correction will be 1.682 Tavr b a DelH DelS N P Sp Sf2 1387. -0.54 0.00 1 1430. 0.00 0.11 2 1473. -0.14 0.08 3 1515. -0.49 0.37 2 1461. 2.19 -0.24 -18.2 +/- 62.5 -14.5 +/- 42.8 8.0 0.055 0.20 0.42 All experiments 1461. 2.19 -0.24 -18.2 +/- 62.5 -14.5 +/- 42.8 8.0 0.055 0.20 0.42 Overall there are 9 reactions 16:15:02 Inverting is over 16:15:03 Solution is found 16:15:04 i DelHcor DelHest dif DelScor DelSest dif DelH DelS S1 1 168.1 180.0 -11.9 127.3 128.6 -1.3 -15.7 -6.9 0.28 2 195.9 180.0 15.9 126.5 126.7 -0.2 -15.7 -6.9 0.25 3 171.8 180.0 -8.3 133.2 132.8 0.4 -15.7 -6.9 0.21 4 -53.8 -15.3 -38.5 -12.2 -10.9 -1.3 85.9 -5.9 0.32 5 81.9 -15.3 97.2 -13.8 -10.5 -3.3 85.9 -5.9 1.59 6 6.9 -15.3 22.2 -9.0 -11.3 2.3 85.9 -5.9 1.12 7 9.8 -14.4 24.3 -9.4 -9.9 0.5 -8.8 0.7 0.31 8 -31.8 -14.4 -17.3 -11.0 -10.6 -0.3 -8.8 0.7 0.25 9 -267.5 -326.3 58.8 -223.4 -223.3 0.0 40.6 25.8 0.39 Standart error of fitting is 0.56 Degrees of freedom are 14 DelfHT DelfH0 sr sold ssum MnO2- -196.3 -265.7 4.6 12.0 12.8 MnO3- -441.0 -538.2 5.4 12.6 13.7 MnO4- -547.2 -669.1 8.0 14.7 16.7 PtO2- 0.4 -70.4 7.3 11.9 14.0 S sr sold ssum MnO2- MnO3- MnO4- PtO2- MnO2- 165. 114. 118. 95. MnO3- 114. 188. 148. 112. MnO4- 118. 148. 280. 130. PtO2- 95. 112. 130. 195. MnO(s) 0. 0. 0. 0. Pt(s) 0. 0. 0. 0. CrO3- 49. 54. 59. 54. CrO4- 56. 59. 61. 59. Cr2O6- 49. 50. 51. 51. MnO2- 35. 0. 0. 0. MnO3- 0. 37. 0. -1. MnO4- 0. 0. 66. -1. PtO2- 0. 0. 0. 35. MnO(s) -12. -12. -12. 1. Pt(s) 0. 0. 0. 0. CrO3- -1. 0. 1. 0. CrO4- 1. -2. -5. -2. Cr2O6- 16. 12. 8. 13. All done 16:15:09