11:24:14 12 substances 6 substances with unknown enthalpies 6 substances with unknown entropies name ion M i DelfH0 HT-H0 s(H) ST s(S) V2O5- T 182.0 1.0000 0.0 0.0 0.0 0.0 0.0 V3O8- T 281.0 1.0000 0.0 0.0 0.0 0.0 0.0 VO2- T 83.0 1.0000 0.0 68.5 0.0 0.0 0.0 VO3- T 99.0 1.0000 0.0 95.5 0.0 0.0 0.0 V4O10- T 364.0 1.0000 0.0 366.2 0.0 0.0 0.0 CoO2- T 91.0 1.0000 0.0 70.7 0.0 0.0 0.0 Substances with known enthalpies Substances with known entropies V3O5(s) F 0.0 0.0000 -1674.1 0.0 7.6 463.0 5.5 Cr2O3(s) F 0.0 0.0000 -1134.8 152.1 1.7 268.9 1.3 CoO(s) F 0.0 0.0000 -237.8 70.7 1.3 137.8 1.7 O2 F 0.0 0.0000 0.0 45.6 0.0 255.5 0.0 CrO3- T 100.0 0.8376 -669.0 97.5 9.0 391.7 4.0 CrO4- T 116.0 0.8376 -781.0 119.9 11.0 432.2 5.8 11:24:14 Covariations H and H 57.00 CrO3- 5 CrO4- 6 Covariations H and S 21.00 CrO3- 5 CrO3- 11 44.00 CrO4- 6 CrO4- 12 1.70 V3O5(s) 1 V3O5(s) 7 ( 1) -1. V2O5- -1. V3O8- +1. VO3- +1. V4O10- Sum is 4. Mass correction will be -0.175 Tavr b a DelH DelS N P Sp Sf2 1209. 0.71 0.06 4 1255. 0.62 0.09 6 1300. 0.59 0.04 7 1344. 0.44 0.10 3 1387. 0.40 0.11 3 1255. 0.60 0.11 6 1300. 0.51 0.05 8 1344. 0.50 0.14 9 1387. 0.46 0.18 10 1430. 0.32 0.19 9 1473. 0.10 0.14 10 1515. 0.20 0.23 6 1300. 0.46 0.02 2 1344. 0.40 0.17 6 1387. 0.41 0.16 4 1430. 0.20 0.10 3 1473. 0.24 0.09 4 1255. 0.96 0.09 4 1300. 0.85 0.05 7 1344. 0.63 0.05 5 1387. 0.58 0.02 3 1430. 0.45 0.09 3 1300. 0.86 0.14 3 1344. 0.64 0.16 3 1387. 0.52 0.09 6 1430. 0.47 0.18 3 1455. 0.40 0.00 1 1358. 4.02 0.49 -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 All experiments 1358. 4.02 0.49 -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 ( 2) -1. V3O5(s) -2. VO3- -3. V3O8- +3. V2O5- +2. V4O10- Sum is 26. Mass correction will be 0.255 Tavr b a DelH DelS N P Sp Sf2 1209. -0.17 0.06 4 1255. -0.12 0.06 6 1300. -0.06 0.06 7 1344. -0.03 0.09 3 1387. 0.16 0.03 3 1255. -0.16 0.13 6 1300. -0.12 0.10 8 1344. -0.02 0.15 9 1387. -0.02 0.12 10 1430. 0.11 0.08 9 1473. 0.08 0.14 10 1515. 0.08 0.08 6 1300. -0.07 0.02 2 1344. 0.07 0.13 6 1387. 0.17 0.08 4 1430. 0.16 0.07 3 1473. 0.19 0.08 4 1361. -2.06 0.00 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 All experiments 1361. -2.06 0.00 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 ( 3) -1. Cr2O3(s) -3. VO3- -3. V3O8- +2. CrO3- +2. V2O5- +2. V4O10- Sum is 30. Mass correction will be 0.195 Tavr b a DelH DelS N P Sp Sf2 1255. -0.79 0.02 4 1300. -0.83 0.05 7 1344. -0.75 0.03 5 1387. -0.73 0.01 3 1430. -0.60 0.04 3 1300. -0.97 0.13 3 1344. -0.85 0.02 3 1387. -0.59 0.03 6 1430. -0.68 0.17 3 1455. -0.83 0.00 1 1347. -2.35 -0.75 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 All experiments 1347. -2.35 -0.75 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 ( 4) -8. Cr2O3(s) -30. CrO4- -9. VO3- -29. V2O5- +46. CrO3- +21. V3O8- +1. V4O10- Sum is 4380. Mass correction will be 0.062 Tavr b a DelH DelS N P Sp Sf2 1300. 5.41 0.10 5 1344. 5.18 0.04 5 1387. 5.10 0.04 3 1430. 4.93 0.22 3 1300. 5.31 0.11 3 1344. 5.28 0.04 3 1387. 5.14 0.14 6 1430. 4.99 0.11 3 1455. 4.90 0.00 1 1363. 5.65 5.17 -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 All experiments 1363. 5.65 5.17 -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 ( 5) -13. Cr2O3(s) -53. CrO3- +79. CrO4-+146. VO2--115. VO3--111. V2O5- +25. V3O8- +29. V4O10- Sum is 57378. Mass correction will be -0.054 Tavr b a DelH DelS N P Sp Sf2 1344. -6.39 0.00 1 1387. -7.26 0.09 3 1430. -7.08 0.23 3 1387. -6.35 0.15 6 1430. -6.81 0.23 3 1455. -6.29 0.00 1 1403. 6.76 -6.72 -56.2 +/-108.2 -96.0 +/- 77.1 17.0 0.058 0.18 0.75 All experiments 1403. 6.76 -6.72 -56.2 +/-108.2 -96.0 +/- 77.1 17.0 0.058 0.18 0.75 ( 6) -1. CoO(s) -2. VO3- +1. V2O5- +1. CoO2- Sum is 6. Mass correction will be 0.214 Tavr b a DelH DelS N P Sp Sf2 1370. -4.26 0.04 2 1430. -4.12 0.06 9 1515. -4.13 0.15 12 1467. -0.84 -4.13 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 All experiments 1467. -0.84 -4.13 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 Overall there are 6 reactions 11:24:14 Inverting is over 11:24:14 Solution is found 11:24:14 i DelHcor DelHest dif DelScor DelSest dif DelH DelS S1 1 33.4 33.4 0.0 4.1 4.1 0.0 -33.4 -20.6 0.00 2 311.2 311.2 0.0 332.0 332.0 0.0 17.1 12.6 0.00 3 -48.8 -48.8 0.0 -121.9 -121.9 0.0 19.5 8.3 0.00 4 68.2 68.2 0.0 14.8 14.8 0.0 -46.9 8.6 0.00 5 18.0 18.0 0.0 -124.4 -124.4 0.0 -56.2 -96.0 0.00 6 61.2 61.2 0.0 68.4 68.4 0.0 7.0 -29.6 0.00 Standart error of fitting is 0.00 Degrees of freedom are 0 DelfHT DelfH0 sr sold ssum V2O5- -1211.8 -1211.8 0.0 10.1 10.1 V3O8- -2036.4 -2036.4 0.0 16.3 16.3 VO2- -577.3 -645.8 0.0 16.2 16.2 VO3- -642.4 -737.9 0.0 9.9 9.9 V4O10- -2672.7 -3038.9 0.0 19.8 19.8 CoO2- -222.9 -293.6 0.0 11.4 11.4 S sr sold ssum V2O5- 604.1 0.0 5.1 5.1 V3O8- 843.0 0.0 10.5 10.5 VO2- 197.2 0.0 11.2 11.2 VO3- 392.1 0.0 5.1 5.1 V4O10- 1013.9 0.0 13.4 13.4 CoO2- 245.4 0.0 6.9 6.9 V2O5- V3O8- VO2- VO3- V4O10-CoO2- V2O5- V3O8- VO2- VO3- V4O10-CoO2- V2O5- 102. 102. 101. 92. 112. 82. 17. 3. 30. 20. 0. 23. V3O8- 102. 265. -61. 47. 321. -8. 3. 106. -99. -23. 132. -49. VO2- 101. -61. 264. 137. -97. 173. 30. -99. 159. 62. -131. 94. VO3- 92. 47. 137. 99. 41. 105. 20. -23. 62. 30. -33. 40. V4O10- 112. 321. -97. 41. 392. -31. 0. 132. -131. -33. 165. -67. CoO2- 82. -8. 173. 105. -31. 129. 23. -49. 94. 40. -67. 58. V2O5- 17. 3. 30. 20. 0. 23. 26. 22. 29. 22. 26. 18. V3O8- 3. 106. -99. -23. 132. -49. 22. 110. -66. -7. 140. -37. VO2- 30. -99. 159. 62. -131. 94. 29. -66. 125. 51. -87. 72. VO3- 20. -23. 62. 30. -33. 40. 22. -7. 51. 26. -12. 31. V4O10- 0. 132. -131. -33. 165. -67. 26. 140. -87. -12. 178. -50. CoO2- 23. -49. 94. 40. -67. 58. 18. -37. 72. 31. -50. 48. V3O5(s) 39. 58. 19. 19. 77. 0. 1. 2. 1. 1. 2. 0. Cr2O3(s) -1. -1. -1. -1. -1. -1. 0. 0. 0. 0. 0. 0. CoO(s) 0. 0. 0. 0. 0. 2. 0. 0. 0. 0. 0. 0. O2 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 77. 45. 109. 85. 37. 93. 18. -10. 46. 25. -17. 32. CrO4- 68. 153. -18. 46. 174. 25. 7. 66. -51. -7. 81. -22. V3O5(s) 1. 2. 1. 1. 2. 0. 20. 30. 10. 10. 40. 0. Cr2O3(s) 0. 0. 0. 0. 0. 0. -1. -1. -1. -1. -1. -1. CoO(s) 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 3. O2 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 17. -11. 45. 24. -18. 31. 13. -8. 35. 19. -13. 24. CrO4- 7. 66. -51. -7. 81. -22. 6. 50. -39. -6. 62. -17. All done 11:24:14