11:28:48 12 substances 6 substances with unknown enthalpies 2 substances with unknown entropies name ion M i DelfH0 HT-H0 s(H) ST s(S) V2O5- T 182.0 1.0000 0.0 0.0 0.0 0.0 0.0 V3O8- T 281.0 1.0000 0.0 0.0 0.0 0.0 0.0 Substances with known entropies VO2- T 83.0 1.0000 0.0 68.5 0.0 334.5 2.5 VO3- T 99.0 1.0000 0.0 95.5 0.0 380.0 5.2 V4O10- T 364.0 1.0000 0.0 366.2 0.0 894.5 30.0 CoO2- T 91.0 1.0000 0.0 70.7 0.0 342.4 4.4 Substances with known enthalpies V3O5(s) F 0.0 0.0000 -1674.1 0.0 7.6 463.0 5.5 Cr2O3(s) F 0.0 0.0000 -1134.8 152.1 1.7 268.9 1.3 CoO(s) F 0.0 0.0000 -237.8 70.7 1.3 137.8 1.7 O2 F 0.0 0.0000 0.0 45.6 0.0 255.5 0.0 CrO3- T 100.0 0.8376 -669.0 97.5 9.0 391.7 4.0 CrO4- T 116.0 0.8376 -781.0 119.9 11.0 432.2 5.8 11:28:48 Covariations H and H 57.00 CrO3- 5 CrO4- 6 Covariations H and S 21.00 CrO3- 5 CrO3- 15 44.00 CrO4- 6 CrO4- 16 1.70 V3O5(s) 1 V3O5(s) 11 ( 1) -1. V2O5- -1. V3O8- +1. VO3- +1. V4O10- Sum is 4. Mass correction will be -0.175 Tavr b a DelH DelS N P Sp Sf2 1209. 0.71 0.06 4 1255. 0.62 0.09 6 1300. 0.59 0.04 7 1344. 0.44 0.10 3 1387. 0.40 0.11 3 1255. 0.60 0.11 6 1300. 0.51 0.05 8 1344. 0.50 0.14 9 1387. 0.46 0.18 10 1430. 0.32 0.19 9 1473. 0.10 0.14 10 1515. 0.20 0.23 6 1300. 0.46 0.02 2 1344. 0.40 0.17 6 1387. 0.41 0.16 4 1430. 0.20 0.10 3 1473. 0.24 0.09 4 1255. 0.96 0.09 4 1300. 0.85 0.05 7 1344. 0.63 0.05 5 1387. 0.58 0.02 3 1430. 0.45 0.09 3 1300. 0.86 0.14 3 1344. 0.64 0.16 3 1387. 0.52 0.09 6 1430. 0.47 0.18 3 1455. 0.40 0.00 1 1358. 4.02 0.49 -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 All experiments 1358. 4.02 0.49 -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 ( 2) -1. V3O5(s) -2. VO3- -3. V3O8- +3. V2O5- +2. V4O10- Sum is 26. Mass correction will be 0.255 Tavr b a DelH DelS N P Sp Sf2 1209. -0.17 0.06 4 1255. -0.12 0.06 6 1300. -0.06 0.06 7 1344. -0.03 0.09 3 1387. 0.16 0.03 3 1255. -0.16 0.13 6 1300. -0.12 0.10 8 1344. -0.02 0.15 9 1387. -0.02 0.12 10 1430. 0.11 0.08 9 1473. 0.08 0.14 10 1515. 0.08 0.08 6 1300. -0.07 0.02 2 1344. 0.07 0.13 6 1387. 0.17 0.08 4 1430. 0.16 0.07 3 1473. 0.19 0.08 4 1361. -2.06 0.00 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 All experiments 1361. -2.06 0.00 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 ( 3) -1. Cr2O3(s) -3. VO3- -3. V3O8- +2. CrO3- +2. V2O5- +2. V4O10- Sum is 30. Mass correction will be 0.195 Tavr b a DelH DelS N P Sp Sf2 1255. -0.79 0.02 4 1300. -0.83 0.05 7 1344. -0.75 0.03 5 1387. -0.73 0.01 3 1430. -0.60 0.04 3 1300. -0.97 0.13 3 1344. -0.85 0.02 3 1387. -0.59 0.03 6 1430. -0.68 0.17 3 1455. -0.83 0.00 1 1347. -2.35 -0.75 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 All experiments 1347. -2.35 -0.75 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 ( 4) -8. Cr2O3(s) -30. CrO4- -9. VO3- -29. V2O5- +46. CrO3- +21. V3O8- +1. V4O10- Sum is 4380. Mass correction will be 0.062 Tavr b a DelH DelS N P Sp Sf2 1300. 5.41 0.10 5 1344. 5.18 0.04 5 1387. 5.10 0.04 3 1430. 4.93 0.22 3 1300. 5.31 0.11 3 1344. 5.28 0.04 3 1387. 5.14 0.14 6 1430. 4.99 0.11 3 1455. 4.90 0.00 1 1363. 5.65 5.17 -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 All experiments 1363. 5.65 5.17 -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 ( 5) -13. Cr2O3(s) -53. CrO3- +79. CrO4-+146. VO2--115. VO3--111. V2O5- +25. V3O8- +29. V4O10- Sum is 57378. Tavr b a DelH DelS N P Sp Sf2 1403. -56.2 +/-215.0 -96.0 +/- 12.8 4.2 0.029 0.18 0.75 ( 6) -1. CoO(s) -2. VO3- +1. V2O5- +1. CoO2- Sum is 6. Mass correction will be 0.214 Tavr b a DelH DelS N P Sp Sf2 1370. -4.26 0.04 2 1430. -4.12 0.06 9 1515. -4.13 0.15 12 1467. -0.84 -4.13 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 All experiments 1467. -0.84 -4.13 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 Overall there are 6 reactions 11:28:48 Inverting is over 11:28:48 Solution is found 11:28:48 i DelHcor DelHest dif DelScor DelSest dif DelH DelS S1 1 33.4 32.3 1.2 -633.2 -633.2 0.0 -32.3 -19.7 0.07 2 311.2 315.1 -3.8 130.2 130.2 0.0 13.3 9.8 0.21 3 -48.8 -56.4 7.6 -240.4 -240.4 0.0 27.1 13.9 0.18 4 68.2 91.7 -23.6 52.9 52.9 0.0 -70.5 -8.7 0.42 5 17.9 -94.3 112.2 -254.2 -254.2 0.0 56.0 -16.0 0.39 6 61.2 8.6 52.6 238.9 238.9 0.0 59.6 6.3 0.72 Standart error of fitting is 0.48 Degrees of freedom are 4 DelfHT DelfH0 sr sold ssum V2O5- -1256.8 -1256.8 22.8 13.6 26.5 V3O8- -2172.0 -2172.0 24.4 36.3 43.7 VO2- -384.7 -453.2 10.4 8.7 13.5 VO3- -658.6 -754.1 4.8 10.7 11.8 V4O10- -2834.7 -3200.9 14.4 44.0 46.3 CoO2- -81.5 -152.2 7.7 10.1 12.7 S sr sold ssum V2O5- 570.9 16.0 7.0 17.5 V3O8- 743.0 15.9 24.6 29.3 V2O5- V3O8- VO2- VO3- V4O10-CoO2- V2O5- V3O8- V2O5- 701. 514. 90. 150. 532. 111. 411. 231. V3O8- 514. 1912. 121. 141. 1758. 91. 229. 1167. VO2- 90. 121. 183. 83. 140. 70. -8. 4. VO3- 150. 141. 83. 138. 156. 66. 31. 3. V4O10- 532. 1758. 140. 156. 2140. 96. 214. 1005. CoO2- 111. 91. 70. 66. 96. 161. 30. 14. V2O5- 411. 229. -8. 31. 214. 30. 305. 171. V3O8- 231. 1167. 4. 3. 1005. 14. 171. 860. V3O5(s) 37. 55. 18. 18. 74. 0. 0. 0. Cr2O3(s) -1. -1. -1. -1. -1. -1. 0. 0. CoO(s) 0. 0. 0. 0. 0. 2. 0. 0. O2 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 54. 60. 47. 52. 61. 50. 0. 0. CrO4- 56. 64. 53. 56. 64. 55. -1. 1. VO2- 0. 0. 9. 0. 0. 0. 0. 0. VO3- 31. 5. -2. 36. -1. -4. 23. 4. V4O10- 219. 1004. 7. -1. 1223. 16. 161. 738. CoO2- 0. 0. 0. 0. 0. 28. 0. 0. V3O5(s) -20. -45. -13. -13. -52. 1. 4. -4. Cr2O3(s) 1. 1. 1. 1. 1. 1. 0. 0. CoO(s) 0. 0. 0. 0. 0. -4. 0. 0. O2 0. 0. 0. 0. 0. 0. 0. 0. CrO3- 0. 1. -2. -1. 1. -1. 0. 0. CrO4- -2. -2. 3. 0. -3. 1. -1. 1. All done 11:28:48