13:46:42 12 substances 6 substances with unknown enthalpies 0 substances with unknown entropies name ion M i DelfH0 H1300-H0 s(H) S1300 s(S) Substances with known entropies V2O5- T 182.0 1.0000 0.0 161.2 0.0 559.3 20.0 V3O8- T 281.0 1.0000 0.0 261.1 0.0 732.9 25.0 VO2- T 83.0 1.0000 0.0 62.9 0.0 330.3 2.5 VO3- T 99.0 1.0000 0.0 87.4 0.0 374.0 5.2 V4O10- T 364.0 1.0000 0.0 334.2 0.0 871.3 30.0 CoO2- T 91.0 1.0000 0.0 65.0 0.0 338.2 4.4 Substances with known enthalpies V3O5(s) F 0.0 0.0000 -1695.7 0.0 7.6 447.2 4.9 Cr2O3(s) F 0.0 0.0000 -1134.8 139.0 2.0 259.2 1.3 CoO(s) F 0.0 0.0000 -237.8 64.8 1.3 133.4 1.7 O2 F 0.0 0.0000 0.0 42.0 0.0 252.8 0.0 CrO3- T 100.0 0.8376 -669.0 89.4 9.0 385.7 4.0 CrO4- T 116.0 0.8376 -781.0 109.4 11.0 424.4 5.8 13:46:43 Covariations H and H 59.00 CrO3- 5 CrO4- 6 Covariations H and S 21.00 CrO3- 5 CrO3- 17 44.00 CrO4- 6 CrO4- 18 1.70 V3O5(s) 1 V3O5(s) 13 ( 1) -1. V2O5- -1. V3O8- +1. VO3- +1. V4O10- Sum is 4. Mass correction will be -0.175 Tavr DelH DelS N P Sp Sf2 1209. 0.71 0.06 4 1255. 0.62 0.09 6 1300. 0.59 0.04 7 1344. 0.44 0.10 3 1387. 0.40 0.11 3 1255. 0.60 0.11 6 1300. 0.51 0.05 8 1344. 0.50 0.14 9 1387. 0.46 0.18 10 1430. 0.32 0.19 9 1473. 0.10 0.14 10 1515. 0.20 0.23 6 1300. 0.46 0.02 2 1344. 0.40 0.17 6 1387. 0.41 0.16 4 1430. 0.20 0.10 3 1473. 0.24 0.09 4 1255. 0.96 0.09 4 1300. 0.85 0.05 7 1344. 0.63 0.05 5 1387. 0.58 0.02 3 1430. 0.45 0.09 3 1300. 0.86 0.14 3 1344. 0.64 0.16 3 1387. 0.52 0.09 6 1430. 0.47 0.18 3 1455. 0.40 0.00 1 1358. -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 All experiments 1358. -33.4 +/- 4.7 -20.6 +/- 3.5138.0 0.486 0.13 0.28 ( 2) -1. V3O5(s) -2. VO3- -3. V3O8- +3. V2O5- +2. V4O10- Sum is 26. Mass correction will be 0.255 Tavr DelH DelS N P Sp Sf2 1209. -0.17 0.06 4 1255. -0.12 0.06 6 1300. -0.06 0.06 7 1344. -0.03 0.09 3 1387. 0.16 0.03 3 1255. -0.16 0.13 6 1300. -0.12 0.10 8 1344. -0.02 0.15 9 1387. -0.02 0.12 10 1430. 0.11 0.08 9 1473. 0.08 0.14 10 1515. 0.08 0.08 6 1300. -0.07 0.02 2 1344. 0.07 0.13 6 1387. 0.17 0.08 4 1430. 0.16 0.07 3 1473. 0.19 0.08 4 1361. 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 All experiments 1361. 17.1 +/- 2.8 12.6 +/- 2.0100.0 0.444 0.11 0.15 ( 3) -1. Cr2O3(s) -3. VO3- -3. V3O8- +2. CrO3- +2. V2O5- +2. V4O10- Sum is 30. Mass correction will be 0.195 Tavr DelH DelS N P Sp Sf2 1255. -0.79 0.02 4 1300. -0.83 0.05 7 1344. -0.75 0.03 5 1387. -0.73 0.01 3 1430. -0.60 0.04 3 1300. -0.97 0.13 3 1344. -0.85 0.02 3 1387. -0.59 0.03 6 1430. -0.68 0.17 3 1455. -0.83 0.00 1 1347. 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 All experiments 1347. 19.5 +/- 7.8 8.3 +/- 5.8 38.0 0.193 0.07 0.18 ( 4) -8. Cr2O3(s) -30. CrO4- -9. VO3- -29. V2O5- +46. CrO3- +21. V3O8- +1. V4O10- Sum is 4380. Mass correction will be 0.062 Tavr DelH DelS N P Sp Sf2 1300. 5.41 0.10 5 1344. 5.18 0.04 5 1387. 5.10 0.04 3 1430. 4.93 0.22 3 1300. 5.31 0.11 3 1344. 5.28 0.04 3 1387. 5.14 0.14 6 1430. 4.99 0.11 3 1455. 4.90 0.00 1 1363. -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 All experiments 1363. -46.9 +/- 5.0 8.6 +/- 3.7 32.0 0.147 0.11 0.09 ( 5) -13. Cr2O3(s) -53. CrO3- +79. CrO4-+146. VO2--115. VO3--111. V2O5- +25. V3O8- +29. V4O10- Sum is 57378. Tavr DelH DelS N P Sp Sf2 1403. -56.2 +/-215.0 -96.0 +/- 12.8 4.3 0.029 0.18 0.75 ( 6) -1. CoO(s) -2. VO3- +1. V2O5- +1. CoO2- Sum is 6. Mass correction will be 0.214 Tavr DelH DelS N P Sp Sf2 1370. -4.26 0.04 2 1430. -4.12 0.06 9 1515. -4.13 0.15 12 1467. 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 All experiments 1467. 7.0 +/- 11.3 -29.6 +/- 7.7 23.0 0.114 0.12 0.16 Overall there are 6 reactions 13:46:56 Inverting is over 13:46:56 Solution is found 13:46:58 i DelHcor DelHest dif DelScor DelSest dif DelH DelS S1 1 33.4 37.4 -3.9 27.5 27.5 0.0 -37.4 -23.4 0.23 2 315.5 325.4 -10.0 239.1 239.0 0.0 7.1 5.2 0.53 3 -49.4 -51.2 1.8 -38.0 -38.0 0.0 21.3 9.6 0.04 4 68.9 88.5 -19.6 65.0 65.0 0.0 -66.6 -5.8 0.35 5 17.0 -96.8 113.8 -69.0 -69.0 0.0 57.6 -14.9 0.40 6 63.6 10.6 53.0 7.2 7.2 0.0 60.0 6.6 0.73 Standart error of fitting is 0.44 Degrees of freedom are 6 DelfHT DelfH0 sr sold ssum V2O5- -1272.7 -1433.9 5.9 29.1 29.7 V3O8- -2185.9 -2447.0 11.0 35.7 37.3 VO2- -390.5 -453.4 9.4 8.1 12.4 VO3- -666.9 -754.3 4.4 10.6 11.5 V4O10- -2866.5 -3200.7 13.0 44.2 46.1 CoO2- -87.2 -152.2 6.7 10.3 12.3 S sr sold ssum V2O5- V3O8- VO2- VO3- V4O10-CoO2- V2O5- 883. 179. 81. 107. 245. 134. V3O8- 179. 1393. 107. 117. 348. 66. VO2- 81. 107. 153. 76. 153. 61. VO3- 107. 117. 76. 132. 160. 58. V4O10- 245. 348. 153. 160. 2126. 86. CoO2- 134. 66. 61. 58. 86. 152. V3O5(s) 37. 55. 18. 18. 74. 0. Cr2O3(s) -2. -2. -2. -2. -2. -2. CoO(s) 0. 0. 0. 0. 0. 2. O2 0. 0. 0. 0. 0. 0. CrO3- 54. 63. 45. 52. 65. 49. CrO4- 59. 62. 58. 59. 63. 58. V2O5- 547. 5. -9. 5. 6. 49. V3O8- -12. 831. -6. -10. -17. -7. VO2- 0. 0. 9. 0. 0. 0. VO3- 0. -1. -1. 36. -1. -6. V4O10- 12. 20. 17. 9. 1241. 5. CoO2- 0. 0. 0. 0. 0. 28. V3O5(s) -21. -31. -10. -10. -41. 0. Cr2O3(s) 1. 1. 1. 1. 1. 1. CoO(s) 0. 0. 0. 0. 0. -4. O2 0. 0. 0. 0. 0. 0. CrO3- 0. 1. -2. -1. 1. -1. CrO4- 0. -3. 3. 0. -3. 1. All done 13:47:04